MAGNETIC NANOPARTICLE-ASSISTED REMEDIATION OF PETROLEUM-CONTAMINATED SOILS
Alexandre Loukanov
1 Laboratory of Engineering NanoBiotechnology, Department of Eng. Geoecology, University of Mining and Geology “St. Ivan Rilski”, Sofia, Bulgaria, E-mail: a.loukanov@mgu.bg
2 Department of Chemistry and Materials Science, National Institute of Technology, Gunma College, 580 Toriba, Maebashi, Gunma 371-8530 Japan, E-mail: loukanov@gunma-ct.ac.jp

ABSTRACT: Petroleum contamination in soils, often resulting from mining operations and oil and gas drilling activities, poses a serious threat to environmental and human health. These industrial activities can lead to the release of petroleum hydrocarbons into terrestrial ecosystems, where they persist for extended periods, disrupt ecological functions, and degrade soil and water quality. Therefore, the development of sustainable and effective remediation strategies is essential for mitigating the environmental footprint of resource extraction processes. However, the efficiency of conventional soil remediation methods varies widely – from 20% to over 90% – depending on hydrocarbon type, soil properties, and environmental conditions. These traditional approaches suffer from several critical limitations, including prolonged treatment durations, non-selectivity, high operational and logistical costs, and large land requirements. Moreover, they can disrupt the native soil microbiome, reduce soil fertility, and degrade organic matter, potentially leading to the accumulation of toxic or persistent intermediate compounds. To address these challenges, this paper aims to develop an eco-sustainable and cost-effective alternative remediation method. The study investigates the application of magnetic nanoparticles – specifically magnetite (Fe₃O₄) – as a promising remediation approach for oil-contaminated soils. Due to their high surface area, hydrophobicity, strong adsorption capacity, and ease of recovery via magnetic separation, Fe₃O₄ nanoparticles offer distinct advantages over conventional remediation techniques. The proposed mechanism involves the desorption of hydrocarbons from soil organic matter, subsequent adsorption onto nanoparticle surfaces, and recovery through magnetic separation. Batch experiments were conducted to evaluate the effects of nanoparticle concentration, contact time, and soil pH on the removal efficiency of petroleum hydrocarbons. Results demonstrate that nanoparticles sized between 15–20 nm can achieve up to 47–48% removal of nonpolar petroleum constituents—particularly heavy aliphatic and aromatic hydrocarbons – under optimised conditions. Furthermore, a synergistic approach combining Fe₃O₄ with oxidising agents such as persulphate was explored to enhance the degradation of recalcitrant hydrocarbons and improve nanoparticle recyclability. This research supports the integration of nanotechnology into sustainable remediation practices, particularly within the broader context of environmentally responsible raw material extraction, and contributes to the advancement of clean-up technologies for contamination originating from extractive industries.
Key words: Petroleum spills, contaminated soils, iron oxide nanoparticles, remediation

https://doi.org/10.58903/dw18922073

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